1. 武汉船舶职业技术学院机械工程学院
2. 钦州学院机械及船舶海洋工程学院
3. 海湾安全技术有限公司
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邹新宇, 黄宜军, 丛彦茹, 等. 基于AFM微加工技术制造微结构模板中纳米级高分子聚合物的自组装[J]. 机械强度, 2019,41(1):85-90.
ZOU XinYu, HUANG YiJun, CONG YanRu, et al. SELF-ASSEMBLY OF NANOSCALE POLYMER DOMAINS IN MICROSTRUCTURE TEMPLATE MADE BY AFM MICROMACHINING TECHNIQUE[J]. 2019,41(1):85-90.
邹新宇, 黄宜军, 丛彦茹, 等. 基于AFM微加工技术制造微结构模板中纳米级高分子聚合物的自组装[J]. 机械强度, 2019,41(1):85-90. DOI: 10.16579/j.issn.1001.9669.2019.01.015.
ZOU XinYu, HUANG YiJun, CONG YanRu, et al. SELF-ASSEMBLY OF NANOSCALE POLYMER DOMAINS IN MICROSTRUCTURE TEMPLATE MADE BY AFM MICROMACHINING TECHNIQUE[J]. 2019,41(1):85-90. DOI: 10.16579/j.issn.1001.9669.2019.01.015.
介绍一种利用非对称聚合的三嵌段共聚物(SEBS(Styrene-Ethylene-Butylene-Styrene(SEBS))苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚物)自组装特性制造大规模整齐排列纳米阵列的分层方法,该方法混合了自下而上/自上而下两种策略。通过AFM(原子力显微镜)获得的硅基上各式各样的微观结构被用来作为球形和高长径比圆柱形聚合物排列的模板。通过原子力显微镜微加工技术的引入,实现了多畴有序阵列的定向排列,并利用硅基的形貌来控制三嵌段共聚物的自组装过程。这种"图外延"的方法可以被应用在软硬混合的情况下,即凝聚态物质系统。此外,自上而下和自下而上方法的混合运用,是一种新颖的实现分子自组装和普遍采用的形态学约束相并行的有效办法,同时也是实现二者并行的基础及沟通桥梁。
A mixed top-down/bottom-up hierarchical method was introduced to manufacture massively aligned nanoscale domains’ arrays by using the self-assembly of asymmetrical poly( styrene-block-ethylene/butylene’s-block-styrene)( SEBS)triblock copolymers. Silicon substrates of assorted microstructure that is made by AFM that machines approach is used to template the ball-shaped and high-aspect-ratio cylindrical polymer domains’ alignment. The poly domains’ regular arrays were orientated via AFM micromachining technique’s introduction as an implement for dominating triblock copolymers’ self-assembly procedure locally by using the silicon substrate’s topography. This graph epitaxial methodology is exploitable in interbred hard/soft that is condensed substance systems for a variety of applications. Furthermore,pairing bottom-up and top-down methods is a bright,and perhaps basic,bridge between the parallel self-assembly of molecules and the morphological constraint of prevailing technology.
自组装聚合物微结构模板AFM加工技术
Self-assemblyPolymerMicrostructure templateAFM machining technique
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